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991.
Masahide Ohno 《Journal of Electron Spectroscopy and Related Phenomena》2007,160(1-3):15-21
The quasi-particle approximation for the 4p4d state of the metallic elements around Cd breaks down because of very rapid 4p4d–4d3 super Coster–Kroning (sCK) decay of the 4p hole in the presence of the spectator 4d hole. Here the underbar is a hole. As a result, the 4p4d multiplet coupling breaks down. We can examine the presence or absence of the 4p4d multiplet by Auger-electron sCK-electron coincidence spectroscopy measurement of the 3d–4p4d–4d3 Auger-preceded sCK transitions. We collect the sCK-electrons in coincidence with the Auger-electrons of a selected kinetic energy (KE) and vice versa. If the multiplet coupling breaks down and does not exist, the coincidence sCK-electron (or Auger-electron) lines shift as much as the Auger-electron (or sCK-electron) analyzer's selected KE is varied. We can determine not only the three 4d-hole sCK final-state energy but also the presence or absence of the 4p4d multiplet by Auger-electron sCK-electron coincidence spectroscopy. The unique capability of the coincidence measurement by which one can determine the correlation between an Auger-electron and a sCK electron generated, respectively, by creation and annihilation of the same Auger two-hole final state is very useful, even when the quasi-particle approximation of the two-hole state breaks down. 相似文献
992.
The heat capacity of the liquid–liquid mixture isobutyric acid–water has been measured for the first time near and far away from its critical point using an adiabatic calorimeter. The measurements were performed at atmospheric pressure, in the one phase region as a function of three temperatures: (1) T − TC = 0.055 °C, (2) T − TC = 3.055 °C, (3) T − TC = 8.055 °C and of the composition X in acid (IA). The heat capacity Cp decreases rapidly when X increases at the used temperatures. Near the critical composition, Cp is not affected by the correlation of the concentration fluctuations.
The molar excess heat capacity of the system under investigation was analysed along the phase diagram and considered as a structural transformation effect. 相似文献
993.
应用飞秒时间分辨差异吸收光谱技术对PSⅡ的LHCⅡ三聚体中的能量传递过程进行实验研究,分析得到三组能量传递的时间寿命组分:748 fs、3.28 ps、32.15 ps.其中748 fs的组分为单体内Chl b649分子经Chl b658将能量传递给Chl a665分子的过程;3.28 ps时间常量反映单体内能量从Chl a677向吸收更长波长的Chl a688分子的能量传递过程,以及Chl b643、Chl b658和Chl a668~670分子获得能量的过程;而32.15 ps的时间与三聚体内的单体间的能量传递过程有关. 相似文献
994.
采用飞秒泵浦探测技术研究了紫细菌外周捕光天线LH2中的超快光动力学过程.从B800蓝侧的激发态动力学中观察到B800到B850的能量传递时间,实验结果与理论计算结果的差别说明激发B800时可能引起B850上激子带的直接激发,或存在由B800到B850上激子态的能量传递通道.在B800红侧激发的动力学过程中,漂白信号前端存在的一个快速光吸收信号主要来源于B850上激子带的直接激发.在天然RS601和突变体GM309的LH2中,800 nm激发时的动力学过程都表现为一个类似的光漂白过程,动力学曲线的衰减时间常量在天然LH2中明显快于突变体中,说明在GM309中B800到B850的激发能传递速率有所降低.而在845 nm激发下两个样品中的快过程类似,但慢过程在GM309中有所增快,激发态中的能量重新分布包括逆向的能量传递也受到类胡萝卜素微结构的影响. 相似文献
995.
996.
We have studied the structural behavior of lead monoxide (PbO) as a function of pressure via angular dispersive X-ray diffraction employing two different pressure transmitting media that were quasi-hydrostatic (N2) and non-hydrostatic (MgO), respectively. Besides litharge (-PbO) and massicot (β-PbO), which are both stable at ambient pressure, there is an orthorhombic γ-PbO phase which appears upon application of pressure to -PbO. We have found that the orthorhombic γ-PbO phase is favored by shear stress under non-hydrostatic conditions. -PbO shows strong anisotropy in compressibility. The a-axis is rather incompressible with a linear stiffness coefficient of Ka0=540(30) GPa whereas the c-axis stiffness is Kc0=25(1) GPa. The bulk modulus of -PbO is K0=23.1(3) GPa and its derivative . 相似文献
997.
998.
The high pressure phase transition and elastic behavior of rare earth monoselenides (CeSe, EuSe and LaSe) which crystallize
in a NaCl-structure have been investigated using the three body interaction potential (TBIP) approach. These interactions
arise due to the electronshell deformation of the overlapping ions in crystals. The TBP model consists of a long range Coulomb,
three body interactions and the short range overlap repulsive forces operative up to the second neighboring ions. The authors
of this paper estimated the values of the phase transition pressure and the associated volume collapse to be closer than other
calculations. Thus, the TBIP approach also promises to predict the phase transition pressure and pressure variations of elastic
constants of lanthanide compounds.
相似文献
999.
The spin-1 Ising model with the nearest-neighbour bilinear and biquadratic interactions and single-ion anisotropy is simulated
on a cellular automaton which improved from the Creutz cellular automaton (CCA) for a simple cubic lattice. The simulations
have been made for several k=K/J and d=D/J in the 0≤d<3 and −2≤k≤0 parameter regions. We confirm the existence of the re-entrant and the successive re-entrant phase transitions near the
phase boundary. The phase diagrams characterizing phase transitions are presented for comparison with those obtained from
other calculations. The static critical exponents are estimated within the framework of the finite-size scaling theory at
d=0, 1 and 2 in the interval −2≤k≤0. The results are compatible with the universal Ising critical behavior. 相似文献
1000.
N. Stevanović D. Nikezić 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,42(3):397-406
Collision of swift ions with atoms was considered in this paper. The
projectile and target atoms were modeled as assemblies of quantum
oscillators and it was assumed that both, target and projectile could be
excited or ionized, without charge exchange. The model presented here is an
extension of the one given by Sigmund and Haagerup [Phys. Rev. A 34, 892 (1986)]. The number of electrons bound to the projectile, as a function of the projectile velocity,
was used from Cabrera-Trujillo et al. [Phys. Rev. A 55, 2864 (1997)]. Contributions to energy loss from excitation of the projectile and targets were separately considered. It
has been found that projectile excitation contributes up to 20% to the
total energy loss in the lower energy region. Comparisons with other
authors, including SRIM 2003, are also given and good agreement was found. 相似文献